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Ferrocenyl dendronized polymers

dc.rights.licenseopen
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorBOISSELIER, Elodie
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorSHUN, Anita Chan Kam
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorRUIZ, Jaime
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorBELIN, Colette
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorASTRUC, Didier
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2009
dc.identifier.issn1144-0546
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20638
dc.description.abstractEnStyrenic dendrons functionalized with ferrocenyl and chloromethylsilyl termini were synthesized and polymerized by the AIBN-initiated radical polymerization procedure yielding a ferrocenyl dendronized polymer and a chloromethylsilyl dendronized polymer, respectively. The latter polymer was functionalized with ferrocenyl groups using "click'' chemistry. The ferrocenyl dendronized polymers are soluble in common organic solvents such as tetrahydrofuran, dichloromethane, and chloroform. They show a reversible ferrocenyl wave in cyclic voltammetry (CV) and form derivatized Pt electrodes. Their sizes and shapes were examined by size exclusion chromatography (SEC), atomic force microscopy (AFM), dynamic light scattering (DLS) and DOSY H-1 NMR spectroscopy.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.subject.enELECTRON-RESERVOIR COMPLEXES
dc.subject.enRING-OPENING POLYMERIZATION
dc.subject.enATOMIC-FORCE MICROSCOPY
dc.subject.enDENDRITIC SIDE-GROUPS
dc.subject.enLINEAR-POLYMERS
dc.subject.enPOLY(AMIDOAMINE) DENDRIMERS
dc.subject.enCONVERGENT DENDRONS
dc.subject.enBOND-CLEAVAGE
dc.subject.enSHAPE
dc.subject.enROUTE
dc.title.enFerrocenyl dendronized polymers
dc.typeArticle de revue
dc.identifier.doi10.1039/b819604d
dc.subject.halChimie/Polymères
bordeaux.journalNew Journal of Chemistry
bordeaux.page246-253
bordeaux.volume33
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue25
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00398979
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00398979v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=New%20Journal%20of%20Chemistry&rft.date=2009&rft.volume=33&rft.issue=25&rft.spage=246-253&rft.epage=246-253&rft.eissn=1144-0546&rft.issn=1144-0546&rft.au=BOISSELIER,%20Elodie&SHUN,%20Anita%20Chan%20Kam&RUIZ,%20Jaime&CLOUTET,%20Eric&BELIN,%20Colette&rft.genre=article


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