BOISSELIER, Elodie; SHUN, Anita Chan Kam; RUIZ, Jaime; CLOUTET, Eric; BELIN, Colette; ASTRUC, Didier

doi:10.1039/b819604d

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BOISSELIER, Elodie
Institut des Sciences Moléculaires [ISM]

SHUN, Anita Chan Kam
Institut des Sciences Moléculaires [ISM]

RUIZ, Jaime
Institut des Sciences Moléculaires [ISM]

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New Journal of Chemistry. 2009, vol. 33, n° 25, p. 246-253

Royal Society of Chemistry

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Styrenic dendrons functionalized with ferrocenyl and chloromethylsilyl termini were synthesized and polymerized by the AIBN-initiated radical polymerization procedure yielding a ferrocenyl dendronized polymer and a chloromethylsilyl dendronized polymer, respectively. The latter polymer was functionalized with ferrocenyl groups using "click'' chemistry. The ferrocenyl dendronized polymers are soluble in common organic solvents such as tetrahydrofuran, dichloromethane, and chloroform. They show a reversible ferrocenyl wave in cyclic voltammetry (CV) and form derivatized Pt electrodes. Their sizes and shapes were examined by size exclusion chromatography (SEC), atomic force microscopy (AFM), dynamic light scattering (DLS) and DOSY H-1 NMR spectroscopy.< Leer menos

Palabras clave en inglés

ELECTRON-RESERVOIR COMPLEXES

RING-OPENING POLYMERIZATION

ATOMIC-FORCE MICROSCOPY

DENDRITIC SIDE-GROUPS

LINEAR-POLYMERS

POLY(AMIDOAMINE) DENDRIMERS

CONVERGENT DENDRONS

BOND-CLEAVAGE

SHAPE

ROUTE

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Ferrocenyl dendronized polymers

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