Ferrocenyl dendronized polymers
CLOUTET, Eric
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
< Reduce
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Language
en
Article de revue
This item was published in
New Journal of Chemistry. 2009, vol. 33, n° 25, p. 246-253
Royal Society of Chemistry
English Abstract
Styrenic dendrons functionalized with ferrocenyl and chloromethylsilyl termini were synthesized and polymerized by the AIBN-initiated radical polymerization procedure yielding a ferrocenyl dendronized polymer and a ...Read more >
Styrenic dendrons functionalized with ferrocenyl and chloromethylsilyl termini were synthesized and polymerized by the AIBN-initiated radical polymerization procedure yielding a ferrocenyl dendronized polymer and a chloromethylsilyl dendronized polymer, respectively. The latter polymer was functionalized with ferrocenyl groups using "click'' chemistry. The ferrocenyl dendronized polymers are soluble in common organic solvents such as tetrahydrofuran, dichloromethane, and chloroform. They show a reversible ferrocenyl wave in cyclic voltammetry (CV) and form derivatized Pt electrodes. Their sizes and shapes were examined by size exclusion chromatography (SEC), atomic force microscopy (AFM), dynamic light scattering (DLS) and DOSY H-1 NMR spectroscopy.Read less <
English Keywords
ELECTRON-RESERVOIR COMPLEXES
RING-OPENING POLYMERIZATION
ATOMIC-FORCE MICROSCOPY
DENDRITIC SIDE-GROUPS
LINEAR-POLYMERS
POLY(AMIDOAMINE) DENDRIMERS
CONVERGENT DENDRONS
BOND-CLEAVAGE
SHAPE
ROUTE
Origin
Hal imported