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Porphyrin-Based Hybrid Nanohelices: Cooperative Effect between Molecular and Supramolecular Chirality on Amplified Optical Activity

dc.rights.licenseopenen_US
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorANFAR, Zakaria
dc.contributor.authorKUPPAN, Balamurugan
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorSCALABRE, Antoine
dc.contributor.authorNAG, Rahul
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorPOUGET, Emilie
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorNLATE, Sylvain
dc.contributor.authorMAGNA, Gabriele
dc.contributor.authorDI FILIPPO, Ilaria
dc.contributor.authorMONTI, Donato
dc.contributor.authorNAITANA, Mario
dc.contributor.authorSTEFANELLI, Manuela
dc.contributor.authorNIKONOVICH, Tatsiana
dc.contributor.authorBOROVKOV, Victor
dc.contributor.authorAAV, Riina
dc.contributor.authorPAOLESSE, Roberto
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorODA, Reiko
dc.date.accessioned2025-01-20T14:51:02Z
dc.date.available2025-01-20T14:51:02Z
dc.date.issued2024-01-31
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/204414
dc.description.abstractEnThe development of chiral receptors for discriminating the configuration of the analyte of interest is increasingly urgent in view of monitoring the pollution in water and waste liquids. Here we investigate an easy protocol to immobilize desired non-water soluble receptors inside a water-dispersible chiral nano platform made of silica. This approach induces chirality in the receptors and at the same time makes the dye@nanohelix system dispersed in suspension of water without aggregation. We noted strong induction and amplification of chiroptical activity in both achiral or chiral (proline-based or hemicucurbituril-based) porphyrin derivatives with and without zinc ions once confined and organized in nanometric silica helices. The results clearly demonstrated that the organization-induced chirality amplification of porphyrins dominates the molecular chirality and the amplification is more efficient for more flexible porphyrins (especially free-base and achiral).
dc.language.isoENen_US
dc.subject.enHybrid chiral materials
dc.subject.enSilica nanohelices
dc.subject.enChiral porphyrins
dc.subject.enHemicucurbiturils
dc.subject.enChiral induction
dc.title.enPorphyrin-Based Hybrid Nanohelices: Cooperative Effect between Molecular and Supramolecular Chirality on Amplified Optical Activity
dc.typeArticle de revueen_US
dc.identifier.doi10.1021/acs.jpcb.3c07153en_US
dc.subject.halChimie/Matériauxen_US
dc.description.sponsorshipEuropeH2020 FET-OPENen_US
dc.description.sponsorshipEuropeINnovative chemIcal sensors for enanTioselective detectIon of chiral pOllutantsen_US
bordeaux.journalJOURNAL OF PHYSICAL CHEMISTRY Ben_US
bordeaux.page1550-1556en_US
bordeaux.volume128en_US
bordeaux.hal.laboratoriesCBMN : Chimie & de Biologie des Membranes & des Nano-objets - UMR 5248en_US
bordeaux.issue6en_US
bordeaux.institutionUniversité de Bordeauxen_US
bordeaux.institutionBordeaux INPen_US
bordeaux.institutionCNRSen_US
bordeaux.peerReviewedouien_US
bordeaux.inpressnonen_US
hal.popularnonen_US
hal.audienceInternationaleen_US
hal.exportfalse
dc.rights.ccPas de Licence CCen_US
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=JOURNAL%20OF%20PHYSICAL%20CHEMISTRY%20B&rft.date=2024-01-31&rft.volume=128&rft.issue=6&rft.spage=1550-1556&rft.epage=1550-1556&rft.au=ANFAR,%20Zakaria&KUPPAN,%20Balamurugan&SCALABRE,%20Antoine&NAG,%20Rahul&POUGET,%20Emilie&rft.genre=article


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