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Chiral Generation of Hot Carriers for Polarization-Sensitive Plasmonic Photocatalysis

dc.rights.licenseopenen_US
dc.contributor.authorNEGRIN-MONTECELO, Yoel
dc.contributor.authorMOVSESYAN, Artur
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorGAO, Jie
dc.contributor.authorBURGER, Sven
dc.contributor.authorWANG, Zhiming M.
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorNLATE, Sylvain
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorPOUGET, Emilie
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorODA, Reiko
dc.contributor.authorCOMESANA-HERMO, Miguel
dc.contributor.authorGOVOROV, Alexander O.
dc.contributor.authorCORREA-DUARTE, Miguel A.
dc.date.accessioned2024-11-21T11:58:31Z
dc.date.available2024-11-21T11:58:31Z
dc.date.issued2022-02-02
dc.identifier.issn0002-7863en_US
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/203402
dc.description.abstractEnMastering the manipulation of chirality at the nanoscale has long been a priority for chemists, physicists, and materials scientists, given its importance in the biochemical processes of the natural world and in the development of novel technologies. In this vein, the formation of novel metamaterials and sensing platforms resulting from the synergic combination of chirality and plasmonics has opened new avenues in nano-optics. Recently, the implementation of chiral plasmonic nanostructures in photocatalysis has been proposed theoretically as a means to drive polarization-dependent photochemistry. In the present work, we demonstrate that the use of inorganic nanometric chiral templates for the controlled assembly of Au and TiO2 nanoparticles leads to the formation of plasmon-based photocatalysts with polarization-dependent reactivity. The formation of plasmonic assemblies with chiroptical activities induces the asymmetric formation of hot electrons and holes generated via electromagnetic excitation, opening the door to novel photocatalytic and optoelectronic features. More precisely, we demonstrate that the reaction yield can be improved when the helicity of the circularly polarized light used to activate the plasmonic component matches the handedness of the chiral substrate. Our approach may enable new applications in the fields of chirality and photocatalysis, particularly toward plasmon-induced chiral photochemistry.
dc.description.sponsorshipScience and Engineering for Advanced Materials and devices - ANR-10-LABX-0096en_US
dc.language.isoENen_US
dc.title.enChiral Generation of Hot Carriers for Polarization-Sensitive Plasmonic Photocatalysis
dc.title.alternativeJ. Am. Chem. Soc.en_US
dc.typeArticle de revueen_US
dc.identifier.doi10.1021/jacs.1c10526en_US
dc.subject.halChimie/Matériauxen_US
bordeaux.journalJournal of the American Chemical Societyen_US
bordeaux.page1663-1671en_US
bordeaux.volume144en_US
bordeaux.hal.laboratoriesCBMN : Chimie & de Biologie des Membranes & des Nano-objets - UMR 5248en_US
bordeaux.issue4en_US
bordeaux.institutionUniversité de Bordeauxen_US
bordeaux.institutionBordeaux INPen_US
bordeaux.institutionCNRSen_US
bordeaux.peerReviewedouien_US
bordeaux.inpressnonen_US
hal.popularnonen_US
hal.audienceInternationaleen_US
hal.exportfalse
dc.rights.ccPas de Licence CCen_US
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