Dislodgeable Foliar Residue Measurements and Assessment of Dermal Exposure to Captan for Workers in Apple Orchards
| dc.rights.license | open | en_US |
| hal.structure.identifier | Environnements et Paléoenvironnements OCéaniques [EPOC] | |
| dc.contributor.author | DUPORTE, Geoffroy | |
| hal.structure.identifier | Environnements et Paléoenvironnements OCéaniques [EPOC] | |
| dc.contributor.author | BARRON, Emmanuelle | |
| hal.structure.identifier | Bordeaux population health [BPH] | |
| dc.contributor.author | BUREAU, Mathilde | |
| hal.structure.identifier | Environnements et Paléoenvironnements OCéaniques [EPOC] | |
| dc.contributor.author | LE MENACH, Karyn
IDREF: 256879966 | |
| hal.structure.identifier | Bordeaux population health [BPH] | |
| dc.contributor.author | BALDI, Isabelle | |
| hal.structure.identifier | Environnements et Paléoenvironnements OCéaniques [EPOC] | |
| dc.contributor.author | DEVIER, Marie-Helene | |
| hal.structure.identifier | Environnements et Paléoenvironnements OCéaniques [EPOC] | |
| dc.contributor.author | BUDZINSKI, Hélène
ORCID: 0000-0003-1028-9154 IDREF: 070478090 | |
| dc.date.accessioned | 2024-10-10T13:05:58Z | |
| dc.date.available | 2024-10-10T13:05:58Z | |
| dc.date.issued | 2024-08-06 | |
| dc.identifier.issn | 1520-5851 | en_US |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/202387 | |
| dc.description.abstractEn | Captan dislodgeable foliar residues (DFRs) were determined by following the applications of this fungicide in an apple orchard. The study comprised an investigation of the variability of captan DFR values and 14 days of DFR monitoring to assess kinetic modeling. A method combining solid-phase microextraction (SPME) gas chromatography and high-resolution mass spectrometry (GC-QTOF-MS) was developed for the quantification of captan residues from DFR aqueous extracts. The results evidenced that (1) sampling parameters such as the position of the tree in a row and the height of foliar significantly influenced captan DFR levels (247-1450 ng·cm(-2)), highlighting the need to implement a comprehensive sampling strategy; (2) the DFR captan dissipation kinetic model best matched with a biphasic one, with half-lives of DFR(captan) of 3.4 and 12.8 days, respectively, for the initial rapid phase 1 decline (day 0-5) and the slower phase 2 decline phase (day 6-14). Furthermore, through DFR measurements, the potential dermal exposure (PDE) of workers was assessed using transfer coefficients (TCs) from the literature. Compared to the acceptable operator exposure levels (AOELs), the results showed that the re-entry interval for captan may not sufficiently protect workers whose arms, hands, and legs are not covered. | |
| dc.description.sponsorship | COntinental To coastal Ecosystems: evolution, adaptability and governance - ANR-10-LABX-0045 | en_US |
| dc.description.sponsorship | Initiative d'excellence de l'Université de Bordeaux - ANR-10-IDEX-0003 | en_US |
| dc.language.iso | EN | en_US |
| dc.rights | Attribution-NonCommercial-NoDerivs 3.0 United States | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/us/ | * |
| dc.subject.en | Apple Growing | |
| dc.subject.en | Captan | |
| dc.subject.en | Dislodgeable Foliar Residues | |
| dc.subject.en | Kinetic | |
| dc.subject.en | Re-Entry | |
| dc.subject.en | Worker Exposure | |
| dc.title.en | Dislodgeable Foliar Residue Measurements and Assessment of Dermal Exposure to Captan for Workers in Apple Orchards | |
| dc.title.alternative | Environ Sci Technol | en_US |
| dc.type | Article de revue | en_US |
| dc.identifier.doi | 10.1021/acs.est.3c10542 | en_US |
| dc.subject.hal | Sciences du Vivant [q-bio]/Santé publique et épidémiologie | en_US |
| dc.identifier.pubmed | 39038811 | en_US |
| bordeaux.journal | Environmental Science and Technology | en_US |
| bordeaux.page | 13605-13612 | en_US |
| bordeaux.volume | 58 | en_US |
| bordeaux.hal.laboratories | Bordeaux Population Health Research Center (BPH) - UMR 1219 | en_US |
| bordeaux.issue | 31 | en_US |
| bordeaux.institution | Université de Bordeaux | en_US |
| bordeaux.institution | Bordeaux INP | en_US |
| bordeaux.institution | CNRS | en_US |
| bordeaux.institution | INSERM | en_US |
| bordeaux.team | EPICENE_BPH | en_US |
| bordeaux.peerReviewed | oui | en_US |
| bordeaux.inpress | non | en_US |
| hal.identifier | hal-04730677 | |
| hal.version | 1 | |
| hal.date.transferred | 2024-10-10T13:06:01Z | |
| hal.popular | non | en_US |
| hal.audience | Internationale | en_US |
| hal.export | true | |
| dc.rights.cc | Pas de Licence CC | en_US |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Environmental%20Science%20and%20Technology&rft.date=2024-08-06&rft.volume=58&rft.issue=31&rft.spage=13605-13612&rft.epage=13605-13612&rft.eissn=1520-5851&rft.issn=1520-5851&rft.au=DUPORTE,%20Geoffroy&BARRON,%20Emmanuelle&BUREAU,%20Mathilde&LE%20MENACH,%20Karyn&BALDI,%20Isabelle&rft.genre=article |
