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Design of Potassium‐Selective Mixed Ion/Electron Conducting Polymers

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorVILLARROEL MARQUEZ, Ariana Alejandra
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorSALINAS, Gerardo
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorABARKAN, Myriam
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorIDIR, Maël
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorBROCHON, Cyril
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorHADZIIOANNOU, Georges
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorRAOUX, Matthieu
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorKUHN, Alexander
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorLANG, Jochen
IDREF: 085209600
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
dc.date2020
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2020
dc.identifier.issn1022-1336
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/19688
dc.description.abstractEnAn approach providing cation selective PEDOT:polyelectrolyte mixed conductors is presented in this communication, based on the structural modification of this ambivalent (ionic and electronic conductive) polymer complex. First, an 18-crown-6 moiety was integrated into the styrene sulfonate monomer structure as a specific metal cation scavenger particularly targeting K+ vs Na+ detection. This newly functionalized monomer has been characterized by 1H- NMR titration to evaluate the ion selectivity. Aqueous PEDOT dispersion inks containing the polymeric ion-selective moieties have been designed and their electrical and electrochemical properties have been analysed. These biocompatible inks are the first proof-of-concept step towards ion selectivity in view of their interfacing with biological cells and microorgans of interest in the field of biosensors and physiology.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.subject.enMixed conducting polymers
dc.subject.enPEDOT
dc.subject.encrown-ether
dc.subject.enion sensing
dc.subject.encoulovoltammetry.
dc.subject.en17 coulovoltammetry 18 19
dc.title.enDesign of Potassium‐Selective Mixed Ion/Electron Conducting Polymers
dc.typeArticle de revue
dc.identifier.doi10.1002/marc.202070030
dc.subject.halChimie/Polymères
bordeaux.journalMacromolecular Rapid Communications
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.institutionCNRS
bordeaux.peerReviewedoui
hal.identifierhal-02564999
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02564999v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Rapid%20Communications&rft.date=2020&rft.eissn=1022-1336&rft.issn=1022-1336&rft.au=VILLARROEL%20MARQUEZ,%20Ariana%20Alejandra&SALINAS,%20Gerardo&ABARKAN,%20Myriam&IDIR,%20Ma%C3%ABl&BROCHON,%20Cyril&rft.genre=article


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