MAZEL, Antoine; FORNASARIG, Matteo; OWONA, Josianne; TRUFLANDIER, Lionel; CASTET, Frédéric; ROUGIER, Aline

doi:10.1039/D3DT03822J

Metadatos

Mostrar el registro completo del ítem

Licencia de uso del documento

MAZEL, Antoine
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

FORNASARIG, Matteo
Institut des Sciences Moléculaires [ISM]

OWONA, Josianne
Institut des Sciences Moléculaires [ISM]
Donostia International Physics Center [San Sebastian] [DIPC]

Idioma

Article de revue

Este ítem está publicado en

Dalton Transactions. 2024, vol. 53, n° 4, p. 1657-1662

Royal Society of Chemistry

Resumen en inglés

Due to their verstaility and easy processing, Surface-Anchored Metal-Organic Frameworks (SurMOFs) have received recent interest as promising electrochromic thin films. Herein a step forward in their use and characterization was achieved thanks to the integration of {Zn2(PDICl4)2} SurMOFs in a multi-layer electrochromic device (ECD), based on membrane-like electrolyte. Optical and electrochemical properties of the ECD were fully characterized, revealing a two-step reduction process localized on the organic ligand and involving subsequent near infra-red (NIR) and cyan absorbing states, leading to optical modulation of the films. The species responsible for this absorption were isolated and identified in the reduced states. In parallel to experimental characterization, quantum chemistry was successfully used to investigate the structureproperties relationship of the SurMOF revealing additional information regarding the structure and the local environment of the electrochromic ligand.< Leer menos

DOI

http://dx.doi.org/10.1039/D3DT03822J

Proyecto ANR

Monocouches optiques nonlinéaires photosensibles - ANR-20-CE29-0009
Initiative d'excellence de l'Université de Bordeaux - ANR-10-IDEX-0003

Orígen

Importado de Hal

Centros de investigación

Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB) - UMR 5026