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dc.rights.licenseopenen_US
hal.structure.identifierLaboratoire des Composites Thermostructuraux [LCTS]
dc.contributor.authorFENETAUD, Pierre
hal.structure.identifierLaboratoire des Composites Thermostructuraux [LCTS]
dc.contributor.authorROGER, Jerome
hal.structure.identifierLaboratoire des Composites Thermostructuraux [LCTS]
dc.contributor.authorCHOLLON, Georges
hal.structure.identifierLaboratoire des Composites Thermostructuraux [LCTS]
dc.contributor.authorJACQUES, Sylvain
dc.date.accessioned2023-11-22T09:58:13Z
dc.date.available2023-11-22T09:58:13Z
dc.date.issued2023-11-15
dc.identifier.issn0257-8972en_US
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/186049
dc.description.abstractEnTriethylamine borane (TEAB) complex was studied as a potential precursor for the thermal low pressure chemical vapour deposition (LPCVD) of pure crystalline sp2-hybridised BN. In particular, its thermal decomposition with or without ammonia was characterised from thermodynamic and experimental points of view in the temperature ranges 400–2000 °C and 300–1300 °C, respectively. NH3 plays a role in the gas phase equilibrium by providing a nitriding source that promotes HCN formation at high temperatures. NH3 is also a source of hydrogen for light hydrocarbons formation as it decomposes. It is thus possible to promote gaseous carbon species formation at high temperatures and limit carbon introduction into coatings by adding ammonia. A turbostratic BN coating could be obtained by CVD from a TEAB/NH3/N2 mixture and conditions chosen thanks to the gas phase decomposition study.
dc.language.isoENen_US
dc.subject.enTriethylamine borane
dc.subject.enLPCVD
dc.subject.enBN
dc.subject.enFTIR
dc.subject.enThermodynamics
dc.title.enTriethylamine borane thermal decomposition for BN low pressure chemical vapour deposition
dc.title.alternativeSurf Coat Technolen_US
dc.typeArticle de revueen_US
dc.identifier.doi10.1016/j.surfcoat.2023.129927en_US
dc.subject.halChimieen_US
bordeaux.journalSurface and Coatings Technologyen_US
bordeaux.page129927en_US
bordeaux.volume472en_US
bordeaux.hal.laboratoriesLaboratoire des Composites Thermo Structuraux (LCTS) - UMR 5801en_US
bordeaux.institutionUniversité de Bordeauxen_US
bordeaux.institutionCNRSen_US
bordeaux.institutionCEAen_US
bordeaux.peerReviewedouien_US
bordeaux.inpressnonen_US
bordeaux.identifier.funderIDSafranen_US
bordeaux.import.sourcehal
hal.identifierhal-04257081
hal.version1
hal.popularnonen_US
hal.audienceInternationaleen_US
hal.exportfalse
workflow.import.sourcehal
dc.rights.ccPas de Licence CCen_US
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Surface%20and%20Coatings%20Technology&rft.date=2023-11-15&rft.volume=472&rft.spage=129927&rft.epage=129927&rft.eissn=0257-8972&rft.issn=0257-8972&rft.au=FENETAUD,%20Pierre&ROGER,%20Jerome&CHOLLON,%20Georges&JACQUES,%20Sylvain&rft.genre=article


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