A new highly sensitive cryogenic luminescent MOF thermometer built with pyromellitic acid
hal.structure.identifier | Institut des Matériaux de Nantes Jean Rouxel [IMN] | |
dc.contributor.author | AMIAUD, Thibault | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | JUBERA, Véronique | |
hal.structure.identifier | Institut des Matériaux de Nantes Jean Rouxel [IMN] | |
dc.contributor.author | SERIER-BRAULT, Hélène | |
dc.date.issued | 2023 | |
dc.identifier.issn | 2050-7526 | |
dc.description.abstractEn | A ratiometric thermometer based on a mixed Eu-Tb metal-organic framework is reported with a maximum relative thermal sensitivity of 16.1% K-1 at 11 K making this material one of the best-performing thermometers currently reported in the literature. The sensing mechanism of {[Tb2-xEux(H(2)Btec)(Btec)(H2O)(2)]& BULL;4H(2)O}(n) (Btec = 1,2,4,5 Benzenetetracarboxylic acid) has been attributed to a phonon-assisted energy migration between neighboring Tb3+ ions in the structure. | |
dc.description.sponsorship | MOFs à base de lanthanides pour une application de nanothermomètres luminescents - ANR-18-CE09-0008 | |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry | |
dc.title.en | A new highly sensitive cryogenic luminescent MOF thermometer built with pyromellitic acid | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1039/d3tc02125d | |
dc.subject.hal | Chimie/Matériaux | |
dc.subject.hal | Physique [physics]/Physique [physics]/Instrumentations et Détecteurs [physics.ins-det] | |
bordeaux.journal | Journal of Materials Chemistry C | |
bordeaux.page | 10951-10956 | |
bordeaux.volume | 11 | |
bordeaux.issue | 32 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-04182580 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-04182580v1 | |
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