Directing the Self-Assembly of Aromatic Foldamer Helices using Acridine Appendages and Metal Coordination
| dc.rights.license | open | en_US |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | WANG, Jinhua | |
| dc.contributor.author | WICHER, Barbara | |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | MAURIZOT, Victor | |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | HUC, Ivan | |
| dc.date.accessioned | 2023-03-29T16:45:35Z | |
| dc.date.available | 2023-03-29T16:45:35Z | |
| dc.date.issued | 2022-11-07 | |
| dc.identifier.issn | 0947-6539 | en_US |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/172654 | |
| dc.description.abstractEn | Abstract Folded molecules provide complex interaction interfaces amenable to sophisticated self-assembly motifs. Because of their high conformational stability, aromatic foldamers constitute suitable candidates for the rational elaboration of self-assembled architectures. Several multiturn helical aromatic oligoamides have been synthesized that possess arrays of acridine appendages pointing in one or two directions. The acridine units were shown to direct self-assembly in the solid state via aromatic stacking leading to recurrent helix-helix association patterns under the form of discrete dimers or extended arrays. In the presence of Pd(II), metal coordination of the acridine units overwhelms other forces and generates new metal-mediated multihelical self-assemblies, including macrocycles. These observations demonstrate simple access to different types of foldamer-containing architectures, ranging from discrete objects to 1D and, by extension, 2D and 3D arrays. | |
| dc.language.iso | EN | en_US |
| dc.rights | Attribution 3.0 United States | * |
| dc.rights.uri | http://creativecommons.org/licenses/by/3.0/us/ | * |
| dc.subject.en | Aromatic stacking | |
| dc.subject.en | Foldamer | |
| dc.subject.en | Helical conformation | |
| dc.subject.en | Metal coordination | |
| dc.subject.en | Self-assembly | |
| dc.title.en | Directing the Self-Assembly of Aromatic Foldamer Helices using Acridine Appendages and Metal Coordination | |
| dc.type | Article de revue | en_US |
| dc.identifier.doi | 10.1002/chem.202201345 | en_US |
| dc.subject.hal | Chimie/Matériaux | en_US |
| bordeaux.journal | Chemistry – A European Journal | en_US |
| bordeaux.volume | 28 | en_US |
| bordeaux.hal.laboratories | CBMN : Chimie & de Biologie des Membranes & des Nano-objets - UMR 5248 | en_US |
| bordeaux.issue | 62 | en_US |
| bordeaux.institution | Université de Bordeaux | en_US |
| bordeaux.institution | Bordeaux INP | en_US |
| bordeaux.institution | CNRS | en_US |
| bordeaux.peerReviewed | oui | en_US |
| bordeaux.inpress | non | en_US |
| hal.identifier | hal-04051227 | |
| hal.version | 1 | |
| hal.date.transferred | 2023-03-29T16:45:38Z | |
| hal.export | true | |
| dc.rights.cc | CC BY | en_US |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemistry%20%E2%80%93%20A%20European%20Journal&rft.date=2022-11-07&rft.volume=28&rft.issue=62&rft.eissn=0947-6539&rft.issn=0947-6539&rft.au=WANG,%20Jinhua&WICHER,%20Barbara&MAURIZOT,%20Victor&HUC,%20Ivan&rft.genre=article |
