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Narcissistic Self-Sorting of n-Acene Nano-Ribbons yielding Energy-Transfer and Electroluminescence at p-n Junctions

dc.rights.licenseopenen_US
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorSCHAFER, Philip
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorDE VET, Christiaan
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorGARTZIA-RIVERO, Leire
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorRAFFY, Guillaume
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorKAO, Min-Tzu
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorSCHAFER, Christian
hal.structure.identifierLaboratoire du Futur [LOF]
dc.contributor.authorROMASANTA, Laura
hal.structure.identifierLaboratoire du Futur [LOF]
dc.contributor.authorPAVAGEAU, Bertrand
hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorTSAI, Yu-Tang
hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
dc.contributor.authorHIRSCH, Lionel
IDREF: 111272459
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorBASSANI, Dario
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorDEL GUERZO, Andre
IDREF: 130816779
dc.date.accessioned2023-02-27T14:55:13Z
dc.date.available2023-02-27T14:55:13Z
dc.date.issued2022-06-30
dc.identifier.issn2040-3364en_US
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/172107
dc.description.abstractEnThe 2,3-didecyloxy-derivative of an n-type anthracene (n-BG) and a p-type tetracene (p-R) have been synthesized and their self-assembly into nano-ribbons studied. Hyperspectral fluorescence imaging revealed their narcissistic self-sorting, leading to separated nanoribbons emitting with very different colors (blue or green for n-BG, depending on the growth solvent, and red for p-R). It is unique that the usual origins of self-sorting, such as specific H-bonding, different growth kinetics, or incompatible steric hindrance can be ruled out. Hence, the narcissistic behaviour is herein proposed to originate from a sofar unconsidered cause: the discrepancy between the quadrupolar character of n-BG and dipolar character of p-R. At the pn-junctions of these nanoribbons, inter-ribbon FRET and electro-luminescence switch-on were observed by fluorescence microscopy.
dc.description.sponsorshipModulation of Organic Optic Information Interfaces - ANR-06-JCJC-0030en_US
dc.description.sponsorshipFabrication Supramoléculaire de Dispositifs OLED Haute Résolution par voie Imprimable - ANR-17-CE24-0033en_US
dc.language.isoENen_US
dc.rightsAttribution-NonCommercial 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/us/*
dc.title.enNarcissistic Self-Sorting of n-Acene Nano-Ribbons yielding Energy-Transfer and Electroluminescence at p-n Junctions
dc.typeArticle de revueen_US
dc.identifier.doi10.1039/D2NR01017Hen_US
dc.subject.halChimieen_US
dc.description.sponsorshipEuropeSoft Materials Advanced Research Training Networken_US
bordeaux.journalNanoscaleen_US
bordeaux.page8951-8958en_US
bordeaux.volume14en_US
bordeaux.hal.laboratoriesIMS : Laboratoire de l'Intégration du Matériau au Système - UMR 5218en_US
bordeaux.issue25en_US
bordeaux.institutionUniversité de Bordeauxen_US
bordeaux.institutionBordeaux INPen_US
bordeaux.institutionCNRSen_US
bordeaux.peerReviewedouien_US
bordeaux.inpressnonen_US
bordeaux.import.sourcehal
hal.identifierhal-03853690
hal.version1
hal.exportfalse
workflow.import.sourcehal
dc.rights.ccPas de Licence CCen_US
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Nanoscale&rft.date=2022-06-30&rft.volume=14&rft.issue=25&rft.spage=8951-8958&rft.epage=8951-8958&rft.eissn=2040-3364&rft.issn=2040-3364&rft.au=SCHAFER,%20Philip&DE%20VET,%20Christiaan&GARTZIA-RIVERO,%20Leire&RAFFY,%20Guillaume&KAO,%20Min-Tzu&rft.genre=article


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