Transient photoluminescence of para-hexaphenyl layers
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en
Article de revue
Ce document a été publié dans
Physical Review B: Condensed Matter and Materials Physics (1998-2015). 2002-06-01, vol. 65, n° 21, p. 4
American Physical Society
Résumé en anglais
Para-hexaphenyl layers exhibit dramatic changes in their steady-state optical and transient photoluminescence (PL) responses when they are grown with different orientations. For a film in which molecules stand perpendicular ...Lire la suite >
Para-hexaphenyl layers exhibit dramatic changes in their steady-state optical and transient photoluminescence (PL) responses when they are grown with different orientations. For a film in which molecules stand perpendicular to the substrate, radiative recombination of intramolecular Frenkel singlet excitons occurs in less than 2 ps. If the layer is grown with molecules lying parallel to the substrate, short-lived and long-lived PL decay components are found. The former is best reproduced with an annihilation rate equation, characteristic of mobile excitons relaxing in 1 ns while the latter, spectrally redshifted, confirms intermolecular exciton migration.< Réduire
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