PARDO, Luis C.; BARRIO, María; TAMARIT, Josep Lluis; LOPEZ, David O.; SALUD, Josep; NÉGRIER, Philippe; MONDIEIG, Denise

doi:10.1016/S0009-2614(02)00271-3

Métadonnées

Afficher la notice complète

Licence d’utilisation du document

PARDO, Luis C.
Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB]

BARRIO, María
Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB]

TAMARIT, Josep Lluis
Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB]

Langue

Article de revue

Ce document a été publié dans

Chemical Physics Letters. 2002, vol. 355, n° 3-4, p. 339-346

Elsevier

Résumé en anglais

Stable and metastable mixed crystals in the orientationally disordered (OD) state of the 2-methyl2-chloro-propane ((CH3)3CCl) + 2,2-dichloropropane (CH3)2CCl2) binary system were characterized from crystallographic and thermodynamic points of view. Large concentration domains of stable rhombohedral (R) and metastable face-centered cubic (FCC) mixed crystals were found despite the non-isomorphism relationship between the stable FCC phase of (CH3)3CCl and the stable R phase of (CH3)2CCl2. In addition, a third OD phase region was observed in the (CH3)2CCl2-rich side of the system. It is simple cubic (SC) and metastable with respect to the stable R phase region. This corresponds to the binary extension of the R–SC stable-metastable relationship found for pure (CH3)2CCl2.< Réduire

Métadonnées

Licence d’utilisation du document

Stable and metastable mixed crystals in the orientationally disordered state of the [(CH3)(3)CCl]+[(CH3)(2)CCl2] system

Langue

Ce document a été publié dans

Résumé en anglais

DOI

Origine

Unités de recherche