YADNUM, Sudarat; ROCHE, Jérome; LEBRAUD, Eric; NÉGRIER, Philippe; GARRIGUE, Patrick; BRADSHAW, Darren; WARAKULWIT, Chompunuch; LIMTRAKUL, Jumras; KUHN, Alexander

doi:10.1002/anie.201400581

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Licence d’utilisation du document

http://creativecommons.org/licenses/by-nc/

YADNUM, Sudarat
Institut des Sciences Moléculaires [ISM]
Department of Chemistry [Bangkok]

ROCHE, Jérome
Institut des Sciences Moléculaires [ISM]

LEBRAUD, Eric
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

Langue

Article de revue

Ce document a été publié dans

Angewandte Chemie International Edition. 2014-04-07, vol. 53, n° 15, p. 4001-4005

Wiley-VCH Verlag

Résumé en anglais

Herein, bipolar electrochemistry is applied in a straightforward way to the site-selective in situ synthesis of metal-organic framework (MOF) structures, which have attracted tremendous interest in recent years because of their significant application potential, ranging from sensing to gas storage and catalysis. The novelty of the presented work is that the deposit can be intentionally confined to a defined area of a substrate without using masks or templates. The intrinsic site-selectivity of bipolar electrochemistry makes it a method of choice to generate, in a highly controlled way, hybrid particles that may have different functionalities combined on the same particle. The wireless nature of electrodeposition allows the potential for mass production of such Janus-type objects.< Réduire

Mots clés en anglais

Metal-organic frameworks

Composites

Electrochemistry

Electrocrystallization

Janus particles

DOI

http://dx.doi.org/10.1002/anie.201400581

Projet Européen

Biomineral-inspired growth and processing of metal-organic frameworks

Project ANR

Procédé de production de particules dissymétriques par électrochimie bipolaire - ANR-11-EMMA-0007

Origine

Importé de hal

Unités de recherche

Laboratoire Ondes et Matière d'Aquitaine (LOMA) - UMR 5798