PANCHENKO, Pavel A.; FEDOROV, Yuri V.; PEREVALOV, Valeri P.; JONUSAUSKAS, Gediminas; FEDOROVA, Olga A.

doi:10.1021/jp9103728

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PANCHENKO, Pavel A.
A. N. Nesmeyanov Institute of Organoelement Compounds [INEOS]

FEDOROV, Yuri V.
A. N. Nesmeyanov Institute of Organoelement Compounds [INEOS]

PEREVALOV, Valeri P.
Mendeleev University of Chemical Technology of Russia

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Journal of Physical Chemistry A. 2010-04-01, vol. 114, n° 12, p. 4118-4122

American Chemical Society

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The investigation of N-phenyl-4-amino- and N-phenyl 4-acetamido-1,8-naphthalimides containing N-benzo- 15-crown-5 ether substituent showed that the presence of ionophoric fragment as N-substituent in naphthalimide molecule provides the design of compound possessing the properties of fluorescent receptor. The addition of metal cations does not change the position of absorption and emission bands but substantial increases the fluorescence intensity. The study of molecules included the theoretical and experimental (optical, NMR) methods, analysis of intramolecular charge (electron) transfer and fluorescence properties in the presence and absence of metal ions.< Réduire

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Cation-Dependent Fluorescent Properties of Naphthalimide Derivatives with N-Benzocrown Ether Fragment

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