Thermochromic and Photoresponsive Cyanometalate Fe/Co Squares: Toward Control of the Electron Transfer Temperature
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en
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Ce document a été publié dans
Journal of the American Chemical Society. 2014-10-23, vol. 136, p. pp. 16854-16864
American Chemical Society
Résumé en anglais
Two structurally related and photoresponsive cyanide-bridged Fe/Co square complexes, {Fe2Co2}, are reported: {[(TpMe)Fe(CN)3]2[Co(bpy)2]2[(TpMe)Fe- (CN)3]2}·12H2O (2) and {[(TpMe)Fe(CN)3]2[Co-(bpy)2]2[BPh4]2}·6MeCN (3), ...Lire la suite >
Two structurally related and photoresponsive cyanide-bridged Fe/Co square complexes, {Fe2Co2}, are reported: {[(TpMe)Fe(CN)3]2[Co(bpy)2]2[(TpMe)Fe- (CN)3]2}·12H2O (2) and {[(TpMe)Fe(CN)3]2[Co-(bpy)2]2[BPh4]2}·6MeCN (3), where TpMe and bpy are hydridotris(3-methylpyrazol-1-yl)borate and 2,2′-bipyridine, respectively.....< Réduire
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