LI, Huan; SUN, Li-Ping; LI, Qiang; XIA, Tian; HUO, Li-Hua; BASSAT, Jean-Marc.; ROUGIER, Aline; FOURCADE, Sébastien; GRENIER, Jean-Claude

doi:10.1016/j.ijhydene.2015.07.133

Métadonnées

Afficher la notice complète

Licence d’utilisation du document

LI, Huan
Key Laboratory of Functional Inorganic Material Chemistry [KLFIMC]

SUN, Li-Ping
Key Laboratory of Functional Inorganic Material Chemistry [KLFIMC]

LI, Qiang
Key Laboratory of Functional Inorganic Material Chemistry [KLFIMC]

Langue

Article de revue

Ce document a été publié dans

International Journal of Hydrogen Energy. 2015-10, vol. 40, n° 37, p. 12761-12769

Elsevier

Résumé en anglais

Double perovskite oxide Pr2NiMnO6 is evaluated as a potential cathode for intermediate-temperature solid oxide fuel cells (IT-SOFCs). The reactivity test indicates that no reaction occurs between Pr2NiMnO6 and CGO at 1200 °C in air. The thermal expansion coefficients (TEC) of Pr2NiMnO6 are 10.6 × 10−6 K−1 in air and 11.5 × 10−6 K−1 in nitrogen atmosphere within a temperature range of 100–800 °C. The electrochemical properties of Pr2NiMnO6 cathode are characterized by ac impedance and dc polarization methods, respectively. The lowest area specific resistance (ARS) is 0.38 Ω cm2 at 700 °C in air. The dependence of ASR with oxygen partial pressure indicates that the charge transfer process is the rate-limiting step for oxygen reduction reaction on Pr2NiMnO6 cathode.< Réduire

Mots clés en anglais

Intermediate-temperature solid oxide fuel cell

Cathode material

Double perovskite

Electrochemical properties

Métadonnées

Licence d’utilisation du document

Electrochemical performance of double perovskite Pr2NiMnO6 as a potential IT-SOFC cathode

Langue

Ce document a été publié dans

Résumé en anglais

Mots clés en anglais

DOI

Origine

Unités de recherche