SKOPAK, Téa; HÉE, Patricia; LEDEMI, Yannick; DUSSAUZE, Marc; KROEKER, Scott; CARDINAL, Thierry; FARGIN, Evelyne; MESSADDEQ, Younès

doi:10.1002/pssc.201600132

Métadonnées

Afficher la notice complète

Licence d’utilisation du document

SKOPAK, Téa
Centre d'optique, photonique et laser
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

HÉE, Patricia
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

LEDEMI, Yannick
Centre d'optique, photonique et laser

Langue

Article de revue

Ce document a été publié dans

Journal of Non-Crystalline Solids. 2017, vol. 455, p. 83-89

Elsevier

Résumé en anglais

A mixture-design method was used as a multivariate data analysis tool to investigate properties of gallate glasses in the GaO3/2–GeO2–NaO1/2 system. The objective was to design compositions having gallium oxide as the main component of the glass expected for further applications like wave guided transmission in the near- and mid-infrared optical domain. Accordingly to this tool a set of glass compositions were defined in a constrained domain of the ternary glass system rich in gallium oxide and prepared by the traditional melt-quenching technique. Sample density, refractive index, multiphonon cut-off wavelength as well as thermal characteristics were measured as representative multiple responses and a linear model fitting those physical properties vs glass composition was established. The obtained model allows to predict and optimize the different responses for any composition in the studied domain and a better understanding of the influence of each glass component on its physical properties. This study demonstrates that gallium-richest compositions lead to an increase in the polarizability and contribute to a slight enlargement of the transmission window which are the primary conditions requested for intended applications. Complementary structural investigation allows to confirm the influence of the component content in the glass composition revealed by the model.< Réduire

Mots clés en anglais

Gallate glass

Mixture design

Properties modelling

Infrared

71Ga NMR

DOI

http://dx.doi.org/10.1002/pssc.201600132

Project ANR

Initiative d'excellence de l'Université de Bordeaux - ANR-10-IDEX-0003

Origine

Importé de hal

Unités de recherche

Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB) - UMR 5026