A reversible metal–ligand bond break associated to a spin-crossover
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | GUIONNEAU, Philippe | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | LE GAC, Frédéric | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | KAIBA, Abdellah | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | COSTA, José Sánchez | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | CHASSEAU, Daniel | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | LÉTARD, Jean-François | |
dc.date.issued | 2007 | |
dc.identifier.issn | 1359-7345 | |
dc.description.abstractEn | The [FeIIL(CN)2]·H2O complex, dicyano[2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene]iron(II) monohydrate, exhibits a thermal induced metal–ligand bond break reversible in the solid state and associated to a spin crossover that corresponds to an unprecedented structurally characterized modification of the coordination metal environment from a hepta-coordinate high spin state to a hexa-coordinate low spin state. | |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry | |
dc.subject.en | Bond breaking | |
dc.subject.en | Spin-crossover | |
dc.subject.en | Iron co-ordination complex | |
dc.subject.en | X-ray diffraction | |
dc.subject.en | Molecular motors | |
dc.title.en | A reversible metal–ligand bond break associated to a spin-crossover | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1039/b707836f | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Chemical Communications | |
bordeaux.page | 3723 - 3725 | |
bordeaux.issue | 36 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00173801 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00173801v1 | |
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