A reversible metal–ligand bond break associated to a spin-crossover
Language
en
Article de revue
This item was published in
Chemical Communications. 2007 n° 36, p. 3723 - 3725
Royal Society of Chemistry
English Abstract
The [FeIIL(CN)2]·H2O complex, dicyano[2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene]iron(II) monohydrate, exhibits a thermal induced metal–ligand bond break reversible in the solid ...Read more >
The [FeIIL(CN)2]·H2O complex, dicyano[2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene]iron(II) monohydrate, exhibits a thermal induced metal–ligand bond break reversible in the solid state and associated to a spin crossover that corresponds to an unprecedented structurally characterized modification of the coordination metal environment from a hepta-coordinate high spin state to a hexa-coordinate low spin state.Read less <
English Keywords
Bond breaking
Spin-crossover
Iron co-ordination complex
X-ray diffraction
Molecular motors
Origin
Hal imported