Thermal and light-induced spin-crossover in salts of the heptadentate complex [tris(4-{pyrazol-3-yl}-3-aza-3-butenyl)amine]iron(II)
Langue
en
Article de revue
Ce document a été publié dans
Dalton Transactions. 2007 n° 38, p. 4276-4285
Royal Society of Chemistry
Résumé en anglais
The syntheses of [FeL][BF4]2·H2O, [FeL][ClO4]2·H2O, [FeL][NO3]2·CH3NO2 and [FeL][CF3SO3]2 (L = tris(4-{pyrazol-3-yl}-3-aza-3-butenyl)amine) are described. The isostructural BF4– and ClO4– salts are high-spin between 5–300 ...Lire la suite >