Air-stable anisotropic monocrystalline nickel nanowires characterized using electron holography
DRISKO, Glenna
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de chimie de coordination [LCC]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de chimie de coordination [LCC]
GATEL, Christophe
Interférométrie, In situ et Instrumentation pour la Microscopie Electronique [CEMES-I3EM]
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Interférométrie, In situ et Instrumentation pour la Microscopie Electronique [CEMES-I3EM]
DRISKO, Glenna
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de chimie de coordination [LCC]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de chimie de coordination [LCC]
GATEL, Christophe
Interférométrie, In situ et Instrumentation pour la Microscopie Electronique [CEMES-I3EM]
< Réduire
Interférométrie, In situ et Instrumentation pour la Microscopie Electronique [CEMES-I3EM]
Langue
en
Article de revue
Ce document a été publié dans
Nano Letters. 2018, vol. 18, n° 3, p. 1733-1738
American Chemical Society
Résumé en anglais
Nickel is capable of discharging electric and magnetic shocks in aerospace materials thanks to its conductivity and magnetism. Nickel nanowires are especially desirable for such an application as electronic percolation can ...Lire la suite >
Nickel is capable of discharging electric and magnetic shocks in aerospace materials thanks to its conductivity and magnetism. Nickel nanowires are especially desirable for such an application as electronic percolation can be achieved without significantly increasing the weight of the composite material. In this work, single-crystal nickel nanowires possessing a homogeneous magnetic field are produced via a metal–organic precursor decomposition synthesis in solution. The nickel wires are 20 nm in width and 1–2 μm in length. The high anisotropy is attained through a combination of preferential crystal growth in the ⟨100⟩ direction and surfactant templating using hexadecylamine and stearic acid. The organic template ligands protect the nickel from oxidation, even after months of exposure to ambient conditions. These materials were studied using electron holography to characterize their magnetic properties. These thin nanowires display homogeneous ferromagnetism with a magnetic saturation (517 ± 80 emu cm–3), which is nearly equivalent to that of bulk nickel (557 emu cm–3). Nickel nanowires were incorporated into carbon composite test pieces and were shown to dramatically improve the electric discharge properties of the composite material.< Réduire
Mots clés en anglais
Nickel
Electric discharge
Electron holography
Ligand stabilization
Magnetism
Nanowires
Project ANR
Initiative d'excellence de l'Université de Bordeaux - ANR-10-IDEX-0003
Origine
Importé de halUnités de recherche