Aromatic δ-peptides: design, synthesis and structural studies of helical, quinoline-derived oligoamide foldamers
hal.structure.identifier | Chimie supramoléculaire biomimétique et bio-organique - Institut Européen de Chimie et Biologie | |
dc.contributor.author | JIANG, Hua | |
hal.structure.identifier | Laboratoire de Pharmacochimie | |
dc.contributor.author | LÉGER, Jean-Michel | |
hal.structure.identifier | Chimie supramoléculaire biomimétique et bio-organique - Institut Européen de Chimie et Biologie | |
dc.contributor.author | DOLAIN, Christel | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | GUIONNEAU, Philippe | |
hal.structure.identifier | Chimie supramoléculaire biomimétique et bio-organique - Institut Européen de Chimie et Biologie | |
dc.contributor.author | HUC, Ivan | |
dc.date.issued | 2003 | |
dc.description.abstractEn | Oligoamides of 8-amino-4-isobutoxy-2-quinolinecarboxylic acid were designed and synthesized, and their helical structures were characterized in the solid state by single crystal X-ray diffraction, and in solution by 1H NMR. The monomer methyl 4-isobutoxy-8-nitro-2-quinolinecarboxylate is easily prepared in three steps from 2-nitroaninile and dimethyl acetylene dicarboxylate. Successive hydrogenations of nitro groups, saponifications of esters and couplings of amines and acids via the acid chlorides gave a dimer, tetramer, hexamer, octamer, and decamer in a convergent fashion... | |
dc.language.iso | en | |
dc.subject.en | Heterocycles | |
dc.subject.en | Conformation analysis | |
dc.subject.en | Helical structures | |
dc.subject.en | Hydrogen bonds | |
dc.subject.en | Supramolecular chemistry | |
dc.title.en | Aromatic δ-peptides: design, synthesis and structural studies of helical, quinoline-derived oligoamide foldamers | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1016/j.tet.2003.08.058 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Tetrahedron / Tetrahedron [London]; Tetrahedron Suppl; Tetrahedron (London) | |
bordeaux.page | 8365-8374 | |
bordeaux.volume | 59 | |
bordeaux.issue | 42 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00177096 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00177096v1 | |
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