Aromatic δ-peptides: design, synthesis and structural studies of helical, quinoline-derived oligoamide foldamers
JIANG, Hua
Chimie supramoléculaire biomimétique et bio-organique - Institut Européen de Chimie et Biologie
Chimie supramoléculaire biomimétique et bio-organique - Institut Européen de Chimie et Biologie
DOLAIN, Christel
Chimie supramoléculaire biomimétique et bio-organique - Institut Européen de Chimie et Biologie
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Chimie supramoléculaire biomimétique et bio-organique - Institut Européen de Chimie et Biologie
JIANG, Hua
Chimie supramoléculaire biomimétique et bio-organique - Institut Européen de Chimie et Biologie
Chimie supramoléculaire biomimétique et bio-organique - Institut Européen de Chimie et Biologie
DOLAIN, Christel
Chimie supramoléculaire biomimétique et bio-organique - Institut Européen de Chimie et Biologie
Chimie supramoléculaire biomimétique et bio-organique - Institut Européen de Chimie et Biologie
HUC, Ivan
Chimie supramoléculaire biomimétique et bio-organique - Institut Européen de Chimie et Biologie
< Reduce
Chimie supramoléculaire biomimétique et bio-organique - Institut Européen de Chimie et Biologie
Language
en
Article de revue
This item was published in
Tetrahedron / Tetrahedron [London]; Tetrahedron Suppl; Tetrahedron (London). 2003, vol. 59, n° 42, p. 8365-8374
English Abstract
Oligoamides of 8-amino-4-isobutoxy-2-quinolinecarboxylic acid were designed and synthesized, and their helical structures were characterized in the solid state by single crystal X-ray diffraction, and in solution by 1H ...Read more >
Oligoamides of 8-amino-4-isobutoxy-2-quinolinecarboxylic acid were designed and synthesized, and their helical structures were characterized in the solid state by single crystal X-ray diffraction, and in solution by 1H NMR. The monomer methyl 4-isobutoxy-8-nitro-2-quinolinecarboxylate is easily prepared in three steps from 2-nitroaninile and dimethyl acetylene dicarboxylate. Successive hydrogenations of nitro groups, saponifications of esters and couplings of amines and acids via the acid chlorides gave a dimer, tetramer, hexamer, octamer, and decamer in a convergent fashion...Read less <
English Keywords
Heterocycles
Conformation analysis
Helical structures
Hydrogen bonds
Supramolecular chemistry
Origin
Hal imported