Colloidal molecules from valence‐endowed nanoparticles by covalent chemistry
ROUET, Pierre-Etienne
Centre de Recherche Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
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Centre de Recherche Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
ROUET, Pierre-Etienne
Centre de Recherche Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
< Réduire
Centre de Recherche Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Langue
en
Article de revue
Ce document a été publié dans
Angewandte Chemie International Edition. 2018-11-26, vol. 57, n° 48, p. 15754-15757
Wiley-VCH Verlag
Résumé en anglais
We demonstrate a simple method to create a variety of silica‐based colloidal molecules through the covalent assembly of site‐specifically functionalized patchy nanoparticles with complementary nanospheres. Colloidal analogues ...Lire la suite >
We demonstrate a simple method to create a variety of silica‐based colloidal molecules through the covalent assembly of site‐specifically functionalized patchy nanoparticles with complementary nanospheres. Colloidal analogues of BeBr2, BBr3 and CBr4 are obtained from sp‐, sp2‐ and sp3‐like particles, while Br2O and NBr3 analogues can be fabricated by varying the relative amounts of both colloidal precursors. We also show that it is possible to attach covalently silica nanospheres of various sizes to one central patchy nanoparticle, which leads to the formation of more complex colloidal molecules, including chiral ones. The possibility to easily extend the strategy to other colloidal precursors which can serve as satellites, for example, ellipsoidal polymer particles or metallic nanoparticles, opens the way to a rich variety of new colloidal analogues of atoms which could serve as building blocks of next generation materials.< Réduire
Mots clés en anglais
colloidal molecules
colloids
nanoparticles
patchy particles
Project ANR
Dilater le système atomique conventionnel à l'échelle colloïdale grâce à des particules préprogrammées pour une valence donnée - ANR-15-CE09-0010
Initiative d'excellence de l'Université de Bordeaux - ANR-10-IDEX-0003
Initiative d'excellence de l'Université de Bordeaux - ANR-10-IDEX-0003
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