BONNET, Marie-Laure; ARONICA, Christophe; CHASTANET, Guillaume; PILET, Guillaume; LUNEAU, Dominique; MATHONIÈRE, Corine; CLÉRAC, Rodolphe; ROBERT, Vincent

doi:10.1021/ic702012r

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BONNET, Marie-Laure
Laboratoire de Chimie - UMR5182 [LC]

ARONICA, Christophe
Laboratoire de Chimie - UMR5182 [LC]
Laboratoire des Multimatériaux et Interfaces [LMI]

CHASTANET, Guillaume
Laboratoire des Multimatériaux et Interfaces [LMI]

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Inorganic Chemistry. 2008, vol. 47, n° 3, p. pp. 1127-1133

American Chemical Society

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The reaction of a tridentate Schiff base LH (L-: 1,1,1-trifluoro-7-(dimethylamino)-4-methyl-5-aza-3-hepten-2-onato) with a Ni(II) salt in the presence of azide salt has led to a new alternating end-on (EO)/end-to-end (EE) azidobridged Ni(II) chain of formula {[Ni2(í1,1-N3)(í1,3-N3)(L)2(MeOH)2]}n. Its originality lies in the presence of single EE and EO coordination modes for the azide. It crystallizes in the C2/c space group, a ) 21.570(7) Å, b ) 10.79(1) Å, c ) 16.154(5) Å, â ) 120.81(2)°, Z ) 4. The chain can be viewed as {Ni2(N3)(L)2(MeOH)2}+ dimeric units linked to each other in a zigzag pattern by the other azide. Magnetic susceptibility and magnetization measurements have been performed and revealed that the chain can magnetically be depicted as isolated {Ni2(N3)} units exhibiting antiferromagnetic interaction (JAF -37 cm-1). Ab initio calculations confirmed the efficient magnetic coupling through the EE bridge and vanishingly small EO {Ni2(í1,1-N3)} interactions.< Réduire

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Molecular Magnetism

chimie des materiaux

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Nickel(II) Chain with Alternating End-On/End-to-End Single Azido Bridges: A Combined Structural, Magnetic, and Theoretical Study

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