M(hfac)2(TTF–py)2 (M = CuII, MnII; HFAC = hexafluoroacetylacetonate and TTF–py = 4-(2-tetrathiafulvalenyl-ethenyl)pyridine): a new approach for π–d interactions in conducting and magnetic molecule based materials
Langue
en
Article de revue
Ce document a été publié dans
Synthetic Metals. 2003, vol. 133-134, p. 505-507
Elsevier
Résumé en anglais
The new coordination complexes M(hfac)2(TTF–py)2 (M = CuII, MnII) in which the paramagnetic transition metal and the organic donor are covalently linked through delocalized π system are prepared aiming with a new approach ...Lire la suite >
The new coordination complexes M(hfac)2(TTF–py)2 (M = CuII, MnII) in which the paramagnetic transition metal and the organic donor are covalently linked through delocalized π system are prepared aiming with a new approach for the occurrence of π–d interactions in conducting and magnetic molecule based materials. The structures, magnetic properties and electrochemical properties were investigated. X-ray structure analysis revealed its structure is favorable for electrical conductivity.< Réduire
Mots clés en anglais
Conducting material
Magnetic material
Organic donor
Paramagnetic transition metal ions
π–d Interactions
Electrical conductivity
Origine
Importé de halUnités de recherche