Quenching the hysteresis in single crystals of a 1D chain iron(II) spin crossover complex
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en
Article de revue
Ce document a été publié dans
European Journal of Inorganic Chemistry. 2008 n° 19, p. 2963-2966
Wiley-VCH Verlag
Résumé en anglais
The unusual grinding effects observed in the 1D spin crossover polymer [FeL(bipy)]n (1), with L being a tetradentate N2O22- coordinating Schiff base type ligand {(3,3)-[1,2-phenylenebis(iminomethylidyne)]bis(2,4-pentaned ...Lire la suite >
The unusual grinding effects observed in the 1D spin crossover polymer [FeL(bipy)]n (1), with L being a tetradentate N2O22- coordinating Schiff base type ligand {(3,3)-[1,2-phenylenebis(iminomethylidyne)]bis(2,4-pentanedionato)(2-)-N,N,O2,O2} and bipy = 4,4-bipyridine, are investigated using magnetic measurements, X-ray powder diffraction and optical reflectivity studies. The observed behaviour can be explained when solvent effects are taken into account.< Réduire
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