Metal-organic magnets with large coercivity and ordering temperatures up to 242°C
hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | PERLEPE, Panagiota | |
hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
dc.contributor.author | OYARZABAL, Itziar | |
hal.structure.identifier | Department of Chemistry [Jyväskylä Univ] [JYU] | |
dc.contributor.author | MAILMAN, Aaron | |
hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | YQUEL, Morgane | |
hal.structure.identifier | European Synchrotron Radiation Facility [ESRF] | |
dc.contributor.author | PLATUNOV, Mikhail | |
hal.structure.identifier | Swiss Norwegian Beamlines | |
dc.contributor.author | DOVGALIUK, Iurii | |
hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
dc.contributor.author | ROUZIÈRES, Mathieu | |
hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
dc.contributor.author | NÉGRIER, Philippe | |
hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
dc.contributor.author | MONDIEIG, Denise | |
hal.structure.identifier | University of Bath [Bath] | |
dc.contributor.author | SUTURINA, Elizaveta | |
hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
dc.contributor.author | DOURGES, Marie-Anne | |
hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
dc.contributor.author | BONHOMMEAU, Sébastien | |
hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
dc.contributor.author | MUSGRAVE, Rebecca | |
hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
hal.structure.identifier | Danmarks Tekniske Universitet = Technical University of Denmark [DTU] | |
dc.contributor.author | PEDERSEN, Kasper | |
hal.structure.identifier | Swiss-Norwegian Beamlines at the European Synchrotron Radiation Facility | |
dc.contributor.author | CHERNYSHOV, Dmitry | |
hal.structure.identifier | European Synchrotron Radiation Facility [Grenoble] [ESRF] | |
dc.contributor.author | WILHELM, Fabrice | |
hal.structure.identifier | European Synchrotron Radiation Facility [Grenoble] [ESRF] | |
dc.contributor.author | ROGALEV, Andrei | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | MATHONIÈRE, Corine | |
hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
dc.contributor.author | CLÉRAC, Rodolphe | |
dc.date.issued | 2020-10-29 | |
dc.identifier.issn | 0036-8075 | |
dc.description.abstractEn | Magnets derived from inorganic materials (e.g., oxides, rare-earth–based, and intermetallic compounds) are key components of modern technological applications. Despite considerable success in a broad range of applications, these inorganic magnets suffer several drawbacks, including energetically expensive fabrication, limited availability of certain constituent elements, high density, and poor scope for chemical tunability. A promising design strategy for next-generation magnets relies on the versatile coordination chemistry of abundant metal ions and inexpensive organic ligands. Following this approach, we report the general, simple, and efficient synthesis of lightweight, molecule-based magnets by postsynthetic reduction of preassembled coordination networks that incorporate chromium metal ions and pyrazine building blocks. The resulting metal-organic ferrimagnets feature critical temperatures up to 242°C and a 7500-oersted room-temperature coercivity. | |
dc.language.iso | en | |
dc.publisher | American Association for the Advancement of Science (AAAS) | |
dc.title.en | Metal-organic magnets with large coercivity and ordering temperatures up to 242°C | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1126/science.abb3861 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Science | |
bordeaux.page | 587-592 | |
bordeaux.volume | 370 | |
bordeaux.issue | 6516 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-02992922 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-02992922v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Science&rft.date=2020-10-29&rft.volume=370&rft.issue=6516&rft.spage=587-592&rft.epage=587-592&rft.eissn=0036-8075&rft.issn=0036-8075&rft.au=PERLEPE,%20Panagiota&OYARZABAL,%20Itziar&MAILMAN,%20Aaron&YQUEL,%20Morgane&PLATUNOV,%20Mikhail&rft.genre=article |
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