SALEK, Guillaume; DEVOTI, Alexis; GARCIA, Alain; GAUDON, Manuel; JUBERA, Veronique; DEMOURGUES, Alain

doi:10.1039/c6ra07607f

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SALEK, Guillaume
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

DEVOTI, Alexis
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

GARCIA, Alain
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

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RSC Advances. 2016, vol. 6, n° 60, p. 55298-55306

Royal Society of Chemistry

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The C-form (SG: Ia[3 with combining macron]) → B-form (SG: C2/m) phase transition of RE2O3 rare earth sesquioxides is described for the first time for face centred cubic–hexagonal close-packed array transformations. Based on XRD data analysis, the temperature of the C → B phase transition in Gd2−xLaxO3 compositions (0 < x < 0.5) was controlled by adjusting the Gd/La atomic ratio and varies between 1100 °C and 1400 °C. Taking into account the various environments of rare earth oxides in C and B allotropic forms, Eu3+ was used as a local probe to obtain photoluminescence spectra (emission and excitation spectra, luminescence decay time curves). The spectra significantly changed during the phase transition, which occurred within a small temperature range. Furthermore, coupling Rietveld XRD data analysis for the long-range order signature with optical emission spectroscopy to probe the local environment provides a clear view of the C → B phase transition, allowing for the design of new highly sensitive thermal sensors at high temperatures.< Réduire

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Tuning the composition of rare earth sesquioxides Gd2-xLaxO3:Eu3+ to control phase transitions at a high temperature to design new highly sensitive luminescence-based thermal sensors

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