Symmetry breaking above room temperature in an Fe(ii) spin crossover complex with an N4O2 donor set.
Langue
en
Article de revue
Ce document a été publié dans
Chemical Communications. 2017, vol. 53, n° 8, p. 1374-1377
Royal Society of Chemistry
Résumé en anglais
[Fe(qsal-Cl)2] is one of the few known Fe(ii) spin crossover compounds with an N4O2 donor atom environment. It shows an abrupt two-step spin transition at 308 and 316 K and importantly, symmetry breaking at the highest ...Lire la suite >