CARRILLO SOLANO, Mercedes Alicia; DUSSAUZE, Marc; VINATIER, Philippe; CROGUENNEC, Laurence; KAMITSOS, Efstratios I.; HAUSBRAND, R.; JAEGERMANN, Wolfram

doi:10.1007/s11581-015-1573-1

Métadonnées

Licence d’utilisation du document

CARRILLO SOLANO, Mercedes Alicia
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Institut für Materialwissenschaft

DUSSAUZE, Marc
Institut des Sciences Moléculaires [ISM]

VINATIER, Philippe
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

Langue

Article de revue

Ce document a été publié dans

Ionics. 2016, vol. 22, n° 4, p. 471-481

Springer Verlag

Résumé en anglais

Lithium ion-conducting glasses attract wide interest for electrochemical applications like efficient energy storage devices. This work presents a structural study on involved bonding units, based on X-ray photoelectron spectroscopy and infrared spectroscopy, of lithium phosphorus oxide and oxynitride amorphous thin films prepared by RF magnetron sputtering. A thorough consideration of the mid- and far-infrared spectral regions demonstrated structural changes at the phosphate units and the lithium ion environments triggered by nitrogen incorporation and post-deposition thermal treatment. It was found that films prepared by sputtering in pure nitrogen atmosphere have about 75 % of their nitrogen atoms in sites doubly coordinated with phosphorus (P–N=P), and the rest in triply coordinated sites. It was shown also that nitrogen incorporation favors the stability of lithium ions, while annealing enhances ionic conductivity of the oxynitride films.< Réduire

Mots clés en anglais

LiPON

IR spectroscopy

Thin film

Lithium phosphorus oxynitride

Glasses

Métadonnées

Licence d’utilisation du document

Phosphate structure and lithium environments in lithium phosphorus oxynitride amorphous thin films

Langue

Ce document a été publié dans

Résumé en anglais

Mots clés en anglais

DOI

Origine

Unités de recherche