SILAR deposition of Ni(bpy)3X: {X = (NCS)2, (Fe(CN)5NO), and (Ag(CN)2)2} thin films on glass substrates
Langue
en
Article de revue
Ce document a été publié dans
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 2016, vol. 46, n° 12, p. 1741-1750
Taylor & Francis: STM, Behavioural Science and Public Health Titles
Résumé en anglais
The authors focused on the preparation of thin layers based on hybrid materials (organometallic complexes) deposited onto glass substrates. The deposition experiments of [Ni(bpy)3](NCS)2, [Ni(bpy)3](Ag(CN)2)2, and ...Lire la suite >
The authors focused on the preparation of thin layers based on hybrid materials (organometallic complexes) deposited onto glass substrates. The deposition experiments of [Ni(bpy)3](NCS)2, [Ni(bpy)3](Ag(CN)2)2, and [Ni(bpy)3](Fe(CN)5NO) were performed on glass slides (18 mm × 18 mm) by successive ionic layer adsorption and reaction (SILAR) method. The influence of some parameters, such as dipping cycle numbers (30, 60, and 120 dipping cycles), temperature (20°C, 30°C, 40°C, and 50°C), precursors concentration (10−3, 10−2, and 10−1 M), and the nature of the counteranions (NCS−, [Fe(CN)5NO]−2, [Ag(CN)2]−) were studied. Different methods (UV-Vis, SEM, FTIR, and XRD) were used to characterize the deposited layers to determine the absorption coefficient (α) and gap energy (Eg) of the materials.< Réduire
Mots clés en anglais
SILAR
thin films
optical proprieties
Ni(II)
complexes
Complexes
Origine
Importé de halUnités de recherche