Cooperative 1D triazole-based spin crossover FeII material with exceptional mechanical resilience
Langue
en
Article de revue
Ce document a été publié dans
Chemistry of Materials. 2017, vol. 29, n° 2, p. 490-494
American Chemical Society
Résumé en anglais
The magnetic spin change associated with the spin crossover (SCO) phenomenon represents a paradigm of bistability at the molecular level that is of current interest because of potential applications in the development of ...Lire la suite >
The magnetic spin change associated with the spin crossover (SCO) phenomenon represents a paradigm of bistability at the molecular level that is of current interest because of potential applications in the development of new generations of electronic devices such as nonvolatil memories, molecular sensors and displays.(1-5) The SCO phenomenon is especially observed in FeII complexes in which the paramagnetic high spin state (HS, S = 2) can be switched reversibly to the low spin state (LS, S = 0) by several external stimuli such as temperature, pressure or light irradiation.(6) A huge effort has been devoted to the understanding of the transition mechanisms using inter alia crystallographic tools...< Réduire
Project ANR
Bistabilité magnétique dans de nouveaux systèmes moléculaires à base de ligands anioniques pontants
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