SAHOO, Prangya Parimita; GAUDIN, Etienne; DARRIET, Jacques; GURU ROW, T. N.

doi:10.1016/j.materresbull.2008.09.022

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SAHOO, Prangya Parimita
Solid State and Structural Chemistry Unit

GAUDIN, Etienne
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

DARRIET, Jacques
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

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Materials Research Bulletin. 2009, vol. 44, n° 4, p. 812-816

Elsevier

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The crystal structure of Pb3BiV3O12 was solved using single-crystal X-ray diffraction technique. The compound crystallizes in the cubic system I43d (No. 220) with eulytite structure with a = 10.7490(7) Å, V = 1241.95(14) Å3 and Z = 4. The final R1 value of 0.0198 (wR2=0.0384) was achieved for 359 independent reflections during the structure refinement. The Pb2+ and Bi3+ cations occupy the special position (16c) while the oxygen anions occupy the general position (48e) in the crystal structure. Unlike many other eulytite compounds, all the crystallographic positions are fully occupied. The structure consists of edge-shared Pb/Bi octahedra linked at the corners to independent [VO4]3− tetrahedra units, generating a eulytite-type network in the crystal lattice.< Réduire

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Inorganic compound

Oxides

Crystal growth

X-ray diffraction

Crystal structure

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The crystal structure of eulytite Pb<sub>3</sub>BiV<sub>3</sub>O<sub>12</sub>

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