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hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorFOUCHÉ, Olivier
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorDEGERT, Jérôme
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorJONUSAUSKAS, Gediminas
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorBALDE, Cherif
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDESPLANCHES, Cédric
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLÉTARD, Jean-François
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorFREYSZ, Eric
dc.date.issued2009
dc.identifier.issn0009-2614
dc.description.abstractEnAt 150 K, we have recorded the evolution of the energy threshold versus the wavelength and the kinetic of formation and relaxation of the spin state phase transition induced by a single laser pulse in the [Fe(PM-BiA)<sub>2</sub>(NCS)<sub>2</sub>] compound. We demonstrate that different absorption bands of the complexes can drive the phase transition. The saturation-energy and the threshold-energy of the laser pulses are not directly related to the absorption cross-section of the sample. Both the switching and the relaxation kinetics are well fitted using two different time-constants. The switching lasts about 50 μs. The relaxation time-constants are independent of the used excitation-wavelength.
dc.language.isoen
dc.publisherElsevier
dc.title.enLaser induced spin state transition: Spectral and temporal evolution
dc.typeArticle de revue
dc.identifier.doi10.1016/j.cplett.2008.12.070
dc.subject.halChimie/Matériaux
bordeaux.journalChemical Physics Letters
bordeaux.page274-278
bordeaux.volume469
bordeaux.issue4-6
bordeaux.peerReviewedoui
hal.identifierhal-00365464
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00365464v1
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