FOUCHÉ, Olivier; DEGERT, Jérôme; JONUSAUSKAS, Gediminas; BALDE, Cherif; DESPLANCHES, Cédric; LÉTARD, Jean-François; FREYSZ, Eric

doi:10.1016/j.cplett.2008.12.070

Metadatos

Mostrar el registro completo del ítem

Licencia de uso del documento

FOUCHÉ, Olivier
Centre de physique moléculaire optique et hertzienne [CPMOH]

DEGERT, Jérôme
Centre de physique moléculaire optique et hertzienne [CPMOH]

JONUSAUSKAS, Gediminas
Centre de physique moléculaire optique et hertzienne [CPMOH]

Idioma

Article de revue

Este ítem está publicado en

Chemical Physics Letters. 2009, vol. 469, n° 4-6, p. 274-278

Elsevier

Resumen en inglés

At 150 K, we have recorded the evolution of the energy threshold versus the wavelength and the kinetic of formation and relaxation of the spin state phase transition induced by a single laser pulse in the [Fe(PM-BiA)<sub>2</sub>(NCS)<sub>2</sub>] compound. We demonstrate that different absorption bands of the complexes can drive the phase transition. The saturation-energy and the threshold-energy of the laser pulses are not directly related to the absorption cross-section of the sample. Both the switching and the relaxation kinetics are well fitted using two different time-constants. The switching lasts about 50 μs. The relaxation time-constants are independent of the used excitation-wavelength.< Leer menos

Metadatos

Licencia de uso del documento

Laser induced spin state transition: Spectral and temporal evolution

Idioma

Este ítem está publicado en

Resumen en inglés

DOI

Orígen

Centros de investigación