BENABDALLAH, Feres; VEBER, Philippe; PRAKASAM, Mythili; VIRAPHONG, Oudomsack; SHIMAMURA, Kiyoshi; MAGLIONE, Mario

doi:10.1063/1.4870933

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BENABDALLAH, Feres
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

VEBER, Philippe
Centre National de la Recherche Scientifique [CNRS]
Universitatea de Vest din Timișoara [România] = West University of Timișoara [Romania] = Université Ouest de Timișoara [Roumanie] [UVT]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

PRAKASAM, Mythili
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

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Journal of Applied Physics. 2014, vol. 115, n° 14, p. 144102

American Institute of Physics

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Optimal properties like piezoelectricity can be found in polarizable materials for which the structure changes sharply under small composition variations in the vicinity of their morphotropic phase boundary or the triple point in their isobaric temperature-composition phase diagram. In the latter, lead-free (Ba0.850Ca0.150)(Ti0.900Zr0.100)O3 ceramics exhibit outstanding piezoelectric coefficients. For the first time, we report the growth of piezoelectric lead-free single crystals in the BaTiO3-BaZrO3-CaTiO3 pseudo-ternary system. The stoichiometry control in the CaO-BaO-TiO2-ZrO2 solid solution led to single crystals with various compositions ranging from (Ba0.857Ca0.143)(Ti0.928Zr0.072)O3 to (Ba0.953Ca0.047)(Ti0.427Zr0.573)O3. We evidenced a continuous cross-over from a ferroelectric state at high titanium content to a relaxor one on increasing the zirconium content. Such a property tuning is rather seldom observed in lead-free ferroelectrics and confirms what was already reported for ceramics. Single crystal with (Ba0.838Ca0.162)(Ti0.854Zr0.146)O3 composition, which has been grown and oriented along [001] crystallographic direction, displayed electromechanical coefficients d31 and k31 of 93 pC.N−1 and 0.18, respectively, near the room temperature (T = 305 K).< Réduire

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Continuous cross-over from ferroelectric to relaxor state and piezoelectric properties of BaTiO3-BaZrO3-CaTiO3 single crystals

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