DHOUIB, Ikram; GUIONNEAU, Philippe; MHIRI, Tahar; ELAOUD, Zakaria

doi:10.24297/jac.v8i2.4044

Métadonnées

Afficher la notice complète

Licence d’utilisation du document

DHOUIB, Ikram

GUIONNEAU, Philippe
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

MHIRI, Tahar

Langue

Article de revue

Ce document a été publié dans

Journal of Advances in Chemistry. 2014, vol. 8, n° 2, p. 1639-1650

Khalsa Publications

Résumé en anglais

Single crystals of [(CH3CH2)4N] Mn1,5 Cl3 4H2O Cl 2(H2O) were grown by the slow evaporation technique and characterized by means of single-crystal X-ray diffraction, FT-IR and Raman spectroscopy. The title compound belongs to the triclinic space group P with the following unit cell dimensions: a =7.5425(4) Å, b=9.8464 Å, c=13.7671(6) Å, α=89.951(3)°,β=89.753(3)°, γ=81.861(3)°, Z=4. These structures have solved using direct methods and refined by least-squares analysis. The structure was solved by the direct method and refined to final R value of 0.0567. The projection of [(CH3CH2)4N] Mn1,5 Cl3 4H2O Cl 2(H2O) in the plan (a,b) shows an arrangement in layers perpendicular to the direction b . The structure consists of infinite parallel two-dimensional planes built connected ions and water molecules by strong O-H...O and O-H...Cl hydrogen bonding.< Réduire

Mots clés en anglais

Hybrid compound

X-ray diffraction

Infrared spectroscopy

Raman spectroscopy

Métadonnées

Licence d’utilisation du document

Synthesis, Crystal Structure and Characterization of [(CH3CH2)4N]Mn1,5Cl34H2OCl2(H2O)

Langue

Ce document a été publié dans

Résumé en anglais

Mots clés en anglais

DOI

Origine

Unités de recherche