Effect of Ni doped BaTiO<sub>3</sub> on the dielectric properties in the Ba(Ni<sub>1/3</sub>Nb<sub>2/3</sub>)<sub><i>x</i></sub>Ti<sub>1−<i>x</i></sub>O<sub>3</sub> solid solution
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en
Article de revue
Ce document a été publié dans
Journal of Alloys and Compounds. 2009, vol. 481, n° 1-2, p. 559-562
Elsevier
Résumé en anglais
New ferroelectric ceramics of ABO<sub>3</sub> perovskite type were synthesized in the Ba(Ni<sub>1/3</sub>Nb<sub>2/3</sub>)<sub><i>x</i></sub>Ti<sub>1−<i>x</i></sub>O<sub>3</sub> (0 ≤ <i>x</i> ≤ 0.2) system by solid state ...Lire la suite >
New ferroelectric ceramics of ABO<sub>3</sub> perovskite type were synthesized in the Ba(Ni<sub>1/3</sub>Nb<sub>2/3</sub>)<sub><i>x</i></sub>Ti<sub>1−<i>x</i></sub>O<sub>3</sub> (0 ≤ <i>x</i> ≤ 0.2) system by solid state reaction technique. The effect of the replacement of titanium by nickel and niobium in the B site on structural and dielectric properties was investigated. For this, we have use X-ray diffraction and dielectric characterizations. Samples in cubic phase were generally obtained with a sintering temperature of 1350 °C. Dielectric measurements revealed that the very small change in composition by the substitution of titanium by nickel and niobium in the BaTiO<sub>3</sub> has a strong influence on the dielectric proprieties: fast decreasing of <i>T</i><sub>C</sub> or <i>T</i><sub>m</sub> (for BaTiO<sub>3</sub> <i>T</i><sub>C</sub> = 340 K, for <i>x</i> = 0.06, <i>T</i><sub>C</sub> = 270 K and for <i>x</i> = 0.16, <i>T</i><sub>m</sub> = 150 K). The evolution from classic ferroelectric behavior for (0 ≤ <i>x</i> < 0.1) to relaxor behavior for (0.1 ≤ <i>x</i> ≤ 0.2) is emphasized.< Réduire
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