Substantial exchange coupling for {Mo-NCS-M} combination: illustration for 1-D [{Mo(NCS)6}{NiL}2(NCS)]n.
Langue
en
Article de revue
Ce document a été publié dans
Chemical Communications. 2010-10-28, vol. 46, n° 40, p. 7519-7521
Royal Society of Chemistry
Résumé en anglais
An antiferromagnetic interaction of J = -51 cm(-1) has been obtained in a NCS-bridged {Mo(III)-Ni} compound (i.e. [{Mo(NCS)(6)}{NiL}(2)(NCS)](n)), a value twice as large as for the homologous {Cr(III)-Ni} derivative. The ...Lire la suite >