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A Symmetry-Breaking Spin-State Transition in Iron(III).
| hal.structure.identifier | SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology | |
| dc.contributor.author | GRIFFIN, Michael | |
| hal.structure.identifier | SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology | |
| dc.contributor.author | SHAKESPEARE, Stephen | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | SHEPHERD, Helena | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | HARDING, Charles J. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LÉTARD, Jean-François | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DESPLANCHES, Cédric | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | GOETA, Andrés E. | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | HOWARD, Judith A. K. | |
| hal.structure.identifier | Institut für Anorganische Chemie | |
| dc.contributor.author | POWELL, Annie K. | |
| hal.structure.identifier | Institut of Inorganic Chemistry | |
| dc.contributor.author | MEREACRE, Valeriu | |
| hal.structure.identifier | Unité de Chimie des Matériaux Inorganiques et Organiques [UCL CMAT] | |
| dc.contributor.author | GARCIA, Yann | |
| hal.structure.identifier | Unité de Chimie des Matériaux Inorganiques et Organiques [UCL CMAT] | |
| dc.contributor.author | NAIK, Anil D. | |
| hal.structure.identifier | SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology | |
| dc.contributor.author | MÜLLER-BUNZ, Helge | |
| hal.structure.identifier | SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology | |
| dc.contributor.author | MORGAN, Grace G. | |
| dc.date.issued | 2011 | |
| dc.identifier.issn | 1433-7851 | |
| dc.description.abstractEn | A two-step magnetic spin transition with accompanying structural phase transitions is reported for the first time for Fe<sup>III</sup>. The transitions are observed at 187 K and 90 K on cooling with a hysteretic transition recorded upon heating during the first crossover at 106 K. The intermediate phase persists over 97 K and contains an unprecedented [HS-HS-LS] motif with tripling of the unit cell | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.title.en | A Symmetry-Breaking Spin-State Transition in Iron(III). | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/anie.201005545 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Angewandte Chemie International Edition | |
| bordeaux.page | 896-900 | |
| bordeaux.volume | 50 | |
| bordeaux.issue | 4 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00559541 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00559541v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.date=2011&rft.volume=50&rft.issue=4&rft.spage=896-900&rft.epage=896-900&rft.eissn=1433-7851&rft.issn=1433-7851&rft.au=GRIFFIN,%20Michael&SHAKESPEARE,%20Stephen&SHEPHERD,%20Helena&HARDING,%20Charles%20J.&L%C3%89TARD,%20Jean-Fran%C3%A7ois&rft.genre=article |
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