Evidence for hydrogen-bond-mediated exchange coupling in an aqua-bridged CuII dimer: synthesis, magnetic study and correlation with density functional calculations
Langue
en
Article de revue
Ce document a été publié dans
European Journal of Inorganic Chemistry. 2006, vol. 2, p. 329-333
Wiley-VCH Verlag
Résumé en anglais
A rare example of a mono-aqua-bridged copper(II) dimer,namely [Cu2(2-H2O)L2(H2O)2](ClO4)2·2H2O (1), has been synthesised and its structure determined by single-crystal X-ray diffraction...
Mots clés en anglais
Bridging ligands
Copper
Density functional calculations
Exchange interactions
Hydrogen bonds