NOZAWA, Koh; GAILHANOU, H.; RAISON, Lydia; PANIZZA, Pascal; USHIKI, Hideharu; DELVILLE, Jean-Pierre; DELVILLE, Marie-Hélène; SELLIER, Elisabeth

doi:10.1021/la048569r

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NOZAWA, Koh
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Centre de physique moléculaire optique et hertzienne [CPMOH]
Laboratory of Molecular Dynamics and Complex Chemical Physics

GAILHANOU, H.
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Centre de physique moléculaire optique et hertzienne [CPMOH]

RAISON, Lydia
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

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Ce document a été publié dans

Langmuir. 2005, vol. 21, n° 4, p. 1516-1523

American Chemical Society

Résumé en anglais

Control over the synthesis of monodisperse silica particles up to mesoscopic scale is generally made difficult due to intrinsic limitation to submicrometric dimensions and secondary nucleation in seeded experiments. To investigate this issue and overcome these difficulties, we have implemented single step processing by quantifying the effects of the progressive addition of a diluted tetraethyl orthosilicate solution in ethanol on the size and monodispersity of silica particles. Contrary to particles grown in seeded polymerization, monodisperse particles with size up to 2 m were synthesized. Moreover, the particles exhibit a final diameter (df), which varies with V-1/3 over more than 2 orders of magnitude in rate of addition (V). On the basis of a kinetic study in the presence of addition showing that particle growth is limited by the diffusion of monomer species, we developed a diffusion-limited growth model to theoretically explain the observed df(V) behavior and quantitatively retrieve the measured amplitude and exponent. Using a single parameter procedure, we can therefore predict and generate in the room temperature range, monodisperse particles of a targeted size by simply adjusting the rate of addition.< Réduire

Mots clés en anglais

Double-jet precipitation

X-ray scattering

Aggregative growth

Monomer-addition

Size dependence

Sphere

Nucleation

Nanoparticles

Kinetics

Hydrolysis

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Smart control of monodisperse Stöber silica particles: effect of reactant addition rate on growth process

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