Mostrar el registro sencillo del ítem

Photomagnetic studies on spin-crossover solid solutions containing two different metal complexes, [Fe(1-bpp)(2)](x)[M(terpy)(2)](1-x)[BF(4)](2) (M = Ru or Co).

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCHASTANET, Guillaume
hal.structure.identifierSchool of Chemistry [Leeds]
dc.contributor.authorTOVEE, Clare A.
hal.structure.identifierSchool of Chemistry [Leeds]
dc.contributor.authorHYETT, Geoffrey
hal.structure.identifierSchool of Chemistry [Leeds]
dc.contributor.authorHALCROW, Malcolm A.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLÉTARD, Jean-François
dc.date.issued2012
dc.identifier.issn1477-9226
dc.description.abstractEnThe photomagnetic properties of two series of spin-crossover solid solutions, [Fe(1-bpp)(2)](x)[Ru(terpy)(2)](1-x)(BF(4))(2) and [Fe(1-bpp)(2)](x)[Co(terpy)(2)](1-x)(BF(4))(2) (1-bpp = 2,6-bis[pyrazol-1-yl]pyridine), have been investigated. For all the materials, the evolution of the T(LIESST) value, the high-spin → low-spin relaxation parameters and the LITH loops were thoroughly studied. Interestingly in the Fe : Co series, along the photo-excitation, cobalt ions are concomitantly converted from low-spin to high-spin states with the iron centres, and also fully relax after light excitation.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.subject.enPhotomagnetic properties
dc.subject.enSpin-crossover
dc.subject.enSolid solutions
dc.subject.enLIESST
dc.title.enPhotomagnetic studies on spin-crossover solid solutions containing two different metal complexes, [Fe(1-bpp)(2)](x)[M(terpy)(2)](1-x)[BF(4)](2) (M = Ru or Co).
dc.typeArticle de revue
dc.identifier.doi10.1039/c2dt12122k
dc.subject.halChimie/Matériaux
bordeaux.journalDalton Transactions
bordeaux.page4896-4902
bordeaux.volume41
bordeaux.issue16
bordeaux.peerReviewedoui
hal.identifierhal-00684070
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00684070v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Dalton%20Transactions&rft.date=2012&rft.volume=41&rft.issue=16&rft.spage=4896-4902&rft.epage=4896-4902&rft.eissn=1477-9226&rft.issn=1477-9226&rft.au=CHASTANET,%20Guillaume&TOVEE,%20Clare%20A.&HYETT,%20Geoffrey&HALCROW,%20Malcolm%20A.&L%C3%89TARD,%20Jean-Fran%C3%A7ois&rft.genre=article


Archivos en el ítem

ArchivosTamañoFormatoVer

No hay archivos asociados a este ítem.

Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem