A family of discrete magnetaically switchable nanoballs
hal.structure.identifier | School of Chemistry | |
dc.contributor.author | DURISKA MARTIN, B. | |
hal.structure.identifier | School of Chemistry | |
dc.contributor.author | NEVILLE, Suzanne M. | |
hal.structure.identifier | School of Chemistry | |
dc.contributor.author | MOUBARAKI, Boujemaa | |
hal.structure.identifier | School of Chemistry | |
dc.contributor.author | MURRAY, Keith S. | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
hal.structure.identifier | Laboratoire de Chimie et Physique des Matériaux [LCPM] | |
dc.contributor.author | BALDÉ, Cherif | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | LÉTARD, Jean-François | |
hal.structure.identifier | School of Chemistry | |
dc.contributor.author | KEPERT, Cameron J. | |
hal.structure.identifier | School of Chemistry | |
dc.contributor.author | BATTEN, Stuart R. | |
dc.date.issued | 2012 | |
dc.identifier.issn | 2192-6506 | |
dc.description.abstractEn | The thermal and light-induced magnetic properties of a family of discrete magnetically switchable "nanoball" species (3 nm in diameter) is reported. The self-assembly of these materials is accomplished by the use of the metallo building block, [Cu([Tp4-py])(NCCH3)] ([Tp4-py]=tris-[3-(4'-pyridyl)pyrazol-1-yl]hydroborate), combined with a [Fe(NCX)2] (X=S, Se and BH3) species. We previously showed that the thiocyanate analogue (Fe(NCS)-nano) undergoes a thermal and light-induced spin crossover (SCO)--the largest such discrete SCO material reported. Now included in this family are the Se and BH3 analogues, Fe(NCSe)-nano and Fe(NCBH3)-nano, which show increased thermal transition temperatures (T1/2=124 K, 162 and 173 K). This variation in transition temperature over the series S | |
dc.language.iso | en | |
dc.publisher | Wiley | |
dc.title.en | A family of discrete magnetaically switchable nanoballs | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1002/cplu.201200123 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | ChemPlusChem | |
bordeaux.page | 616-623 | |
bordeaux.volume | 77 | |
bordeaux.issue | 8 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00747368 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
dc.subject.it | Discrete | |
dc.subject.it | Iron | |
dc.subject.it | LIESST | |
dc.subject.it | Spin crossover | |
dc.subject.it | Supramolecules | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00747368v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=ChemPlusChem&rft.date=2012&rft.volume=77&rft.issue=8&rft.spage=616-623&rft.epage=616-623&rft.eissn=2192-6506&rft.issn=2192-6506&rft.au=DURISKA%20MARTIN,%20B.&NEVILLE,%20Suzanne%20M.&MOUBARAKI,%20Boujemaa&MURRAY,%20Keith%20S.&BALD%C3%89,%20Cherif&rft.genre=article |
Files in this item
Files | Size | Format | View |
---|---|---|---|
There are no files associated with this item. |