DURISKA MARTIN, B.; NEVILLE, Suzanne M.; MOUBARAKI, Boujemaa; MURRAY, Keith S.; BALDÉ, Cherif; LÉTARD, Jean-François; KEPERT, Cameron J.; BATTEN, Stuart R.

doi:10.1002/cplu.201200123

Metadatos

Mostrar el registro completo del ítem

Licencia de uso del documento

DURISKA MARTIN, B.
School of Chemistry

NEVILLE, Suzanne M.
School of Chemistry

MOUBARAKI, Boujemaa
School of Chemistry

Idioma

Article de revue

Este ítem está publicado en

ChemPlusChem. 2012, vol. 77, n° 8, p. 616-623

Wiley

Resumen en inglés

The thermal and light-induced magnetic properties of a family of discrete magnetically switchable "nanoball" species (3 nm in diameter) is reported. The self-assembly of these materials is accomplished by the use of the metallo building block, [Cu([Tp4-py])(NCCH3)] ([Tp4-py]=tris-[3-(4'-pyridyl)pyrazol-1-yl]hydroborate), combined with a [Fe(NCX)2] (X=S, Se and BH3) species. We previously showed that the thiocyanate analogue (Fe(NCS)-nano) undergoes a thermal and light-induced spin crossover (SCO)--the largest such discrete SCO material reported. Now included in this family are the Se and BH3 analogues, Fe(NCSe)-nano and Fe(NCBH3)-nano, which show increased thermal transition temperatures (T1/2=124 K, 162 and 173 K). This variation in transition temperature over the series S< Leer menos

Palabras clave en italiano

Discrete

Iron

LIESST

Spin crossover

Supramolecules

Metadatos

Licencia de uso del documento

A family of discrete magnetaically switchable nanoballs

Idioma

Este ítem está publicado en

Resumen en inglés

Palabras clave en italiano

DOI

Orígen

Centros de investigación