Structural investigation of the photoinduced spin transition in the [Fe(PM-BIA)2(NCS)2] compound
CAILLEAU, Hervé
Groupe matière condensée et matériaux [GMCM]
Non-equilibrium Dynamics Project [ERATO]
< Réduire
Groupe matière condensée et matériaux [GMCM]
Non-equilibrium Dynamics Project [ERATO]
Langue
en
Article de revue
Ce document a été publié dans
Solid State Data - Pt B: Solid State Phenomena. 2006, vol. 112, p. 81-88
Résumé en anglais
We investigated the thermo- and photo-induced phase transitions between low spin (LS) and high spin (HS) states of the mol. crystal of [Fe(PM-BiA)2(NCS)2] in the orthorhombic form, by using X-ray diffraction. The structure ...Lire la suite >
We investigated the thermo- and photo-induced phase transitions between low spin (LS) and high spin (HS) states of the mol. crystal of [Fe(PM-BiA)2(NCS)2] in the orthorhombic form, by using X-ray diffraction. The structure of the photoinduced HS state, generated from the LS state at low temp., is compared to the structures of the HS and LS phases at thermal equil. and to the thermally trapped HS state. The preliminary results presented here show that the structural reorganization is similar in the different HS states.< Réduire
Mots clés en anglais
Phase transition
Photoinduced
Spin crossover
Origine
Importé de halUnités de recherche