"Click" dendrimers as efficient nanoreactors in aqueous solvent: Pd nanoparticle stabilization for sub-ppm Pd catalysis of Suzuki-Miyaura reactions of aryl bromides.
Langue
en
Article de revue
Ce document a été publié dans
Chemical Communications. 2013, vol. 49, n° 74, p. 8169-8171
Royal Society of Chemistry
Résumé en anglais
Palladium nanoparticles (PdNPs) with a size of 1.4 nm are stabilized by dendritic nanoreactors containing 1,2,3-triazole ligands with hydrophilic triethylene glycol (TEG) termini. These PdNPs are stable for months under ...Lire la suite >
Palladium nanoparticles (PdNPs) with a size of 1.4 nm are stabilized by dendritic nanoreactors containing 1,2,3-triazole ligands with hydrophilic triethylene glycol (TEG) termini. These PdNPs are stable for months under air and are extremely active for the Suzuki-Miyaura reactions of aryl bromides down to sub-ppm levels.< Réduire
Mots clés
Aqueous solvent
Nanoparticles
Dendrimers
Catalysis
Origine
Importé de halUnités de recherche